You need to remove the bottom cover, it's just taped on.
Afterwards you can easily access the power port and solder the + and - wire.
The small white part needs a bit of modification with a cutter.
The stand should just click to the hub, otherwise use some double sided tape.
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There is also space for a step-down converter:
aliExpress
Secured with short PCB holder
I tried to use it with a 20V PD module, to have at least 15V at the output port.
Sadly the output module does only support 5, 9, 12 and 20V.
The original power supply only has 14V at 1,1A → 15,4W, the nest hub needs about 2,5 to 4W in idle. You could try to use the original power supply for the output port, but it will not be sufficient for any fast charging.